Switchable Molecules for Molecular Nanoscience

Valence Tautomerism in D‐Block Complexes

Gemma K Gransbury, Colette Boskovic

2021-10-15

<jats:title>Abstract</jats:title> <jats:p>The need for both improved energy efficiency of information communication tech..

Incorporation of Vanadium and Molybdenum into Yttrium-Arsenotungstates Supported by Amino Acid Ligands

FA Bagherjeri, C Ritchie, RW Gable, G Bryant, C Boskovic

2020-03-01

The preference for incorporation of molybdenum over tungsten into specific sites of a family of yttrium-arsenotungstates with amin..

Photocoloration in Hybrid Amino Acid Polyoxometalates

F Akhlaghi Bagherjeri, C Ritchie, RW Gable, C Boskovic

2019-01-31

The study of four different salts of a hybrid glycine–polyoxotungstate has revealed photocoloration that is dependent on the intra..

Rare Earth Polyoxometalates

C Boskovic

2017-09-19

ConspectusLongstanding and important applications make use of the chemical and physical properties of both rare earth metals and p..

Magnetic Excitations in Polyoxotungstate-Supported Lanthanoid Single-Molecule Magnets: An Inelastic Neutron Scattering and ab Initio Study

Michele Vonci, Marcus J Giansiracusa, Willem Van den Heuvel, Robert W Gable, Boujemaa Moubaraki, Keith S Murray, Dehong Yu, Richard A Mole, Alessandro Soncini, Colette Boskovic

2017-01-03

Inelastic neutron scattering (INS) has been used to investigate the crystal field (CF) magnetic excitations of the analogs of the ..

Mixed-Metal Hybrid Polyoxometalates with Amino Acid Ligands: Electronic Versatility and Solution Properties

FA Bagherjeri, M Vonci, EA Nagul, C Ritchie, RW Gable, MB Taylor, G Bryant, SX Guo, J Zhang, PA Aparicio, X López, JM Poblet, C Boskovic

2016-12-05

Eight new members of a family of mixed-metal (Mo,W) polyoxometalates (POMs) with amino acid ligands have been synthesized and inve..

Carbonate-Bridged Lanthanoid Triangles: Single-Molecule Magnet Behavior, Inelastic Neutron Scattering, and Ab Initio Studies

MJ Giansiracusa, M Vonci, W Van Den Heuvel, RW Gable, B Moubaraki, KS Murray, D Yu, RA Mole, A Soncini, C Boskovic

2016-06-06

Optimization of literature synthetic procedures has afforded, in moderate yield, homogeneous and crystalline samples of the five a..

Ab initio calculations as a quantitative tool in the inelastic neutron scattering study of a single-molecule magnet analogue

M Vonci, MJ Giansiracusa, RW Gable, W Van Den Heuvel, K Latham, B Moubaraki, KS Murray, D Yu, RA Mole, A Soncini, C Boskovic

2016-01-01

Ab initio calculations carried out on the Tb analogue of the single-molecule magnet family Na<inf>9</inf>[Ln(W<inf>5</inf>O<inf>18..

Electronic Lability in a Dinuclear Cobalt-Bis(dioxolene) Complex

A Madadi, M Itazaki, RW Gable, B Moubaraki, KS Murray, C Boskovic

2015-10-01

Remarkable electronic lability is evident from a preliminary study of a dinuclear cobalt complex with a bis(dioxolene) bridging li..

Modular Molecules: Site-Selective Metal Substitution, Photoreduction, and Chirality in Polyoxometalate Hybrids

M Vonci, F Akhlaghi Bagherjeri, PD Hall, RW Gable, A Zavras, RAJ O'Hair, Y Liu, J Zhang, MR Field, MB Taylor, J Du Plessis, G Bryant, M Riley, L Sorace, PA Aparicio, X Lõpez, JM Poblet, C Ritchie, C Boskovic

2014-10-20

The first members of a promising new family of hybrid amino acid-polyoxometalates have emerged from a search for modular functiona..

Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands

T Tezgerevska, KG Alley, C Boskovic

2014-06-01

The defining characteristic of a valence tautomeric (VT) transition in a metal complex with a redox-active organic ligand is a sti..

Redox activity and two-step valence tautomerism in a family of dinuclear cobalt complexes with a spiroconjugated bis(dioxolene) ligand

KG Alley, G Poneti, PSD Robinson, A Nafady, B Moubaraki, JB Aitken, SC Drew, C Ritchie, BF Abrahams, RK Hocking, KS Murray, AM Bond, HH Harris, L Sorace, C Boskovic

2013-06-05

A family of dinuclear cobalt complexes with bridging bis(dioxolene) ligands derived from 3,3,3′,3′-tetramethyl-1,1′-spirobis(indan..

A two-step valence tautomeric transition in a dinuclear cobalt complex

KG Alley, G Poneti, JB Aitken, RK Hocking, B Moubaraki, KS Murray, BF Abrahams, HH Harris, L Sorace, C Boskovic

2012-04-02

A dinuclear cobalt complex with cobalt centers bridged by a bis(dioxolene) ligand exhibits a rare two-step valence tautomeric tran..